Effect of hydrophobic interaction cooperating with double Lewis acid activation in a zinc(II) phosphodiesterase mimic.

نویسندگان

  • Meng Zhao
  • Li Zhang
  • Huo-Yan Chen
  • Han-Lu Wang
  • Liang-Nian Ji
  • Zong-Wan Mao
چکیده

The novel dinuclear Zn(ii) complex (1) containing a beta-CD dimer could accelerate BNPP (a DNA substitute) hydrolysis more efficiently than catalyze HPNP (a RNA substitute) transesterification with different mechanisms involved; the beta-CDs played remarkably different roles.

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عنوان ژورنال:
  • Chemical communications

دوره 46 35  شماره 

صفحات  -

تاریخ انتشار 2010